Information card for entry 1100219

Structure parameters

• Chemical name: (μ~3~-Bromo)-tris(μ~3~-tris(dimethylamino)phosphoraneiminato)-tetrabromo-tetra-nickel(ii) dichloromethane solvate
• Formula: C18.75 H55.5 Br5 Cl1.5 N12 Ni4 P3
• Calculated formula: C18 H54 Br5 N12 Ni4 P3
• Title of publication: Phosphaniminato- und Phosphanimin-Komplexe von Nickel(II). Die Kristallstrukturen von [Ni(O~3~SCF~3~)(NPMe~3~)]~4~, [Ni~4~Br~5~{NP(NMe~2~)~3~}~3~], [NiBr~2~{HNP(NMe~2~)~3~}~2~] und [Ni(PMePh~2~)~4~]
• Authors of publication: Krieger, Matthias; Gould, Robert O.; Harms, Klaus; Greiner, Andreas; Dehnicke, Kurt
• Journal of publication: Zeitschrift fuer Anorganische und Allgemeine Chemie
• Year of publication: 2001
• Journal volume: 627
• Journal issue: 4
• Pages of publication: 747 - 754
• a: 12.26 ± 0.003 Å
• b: 16.14 ± 0.003 Å
• c: 24.06 ± 0.005 Å
• α: 90°
• β: 92.34 ± 0.03°
• γ: 90°
• Cell volume: 4756.94 ų
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for significantly intense reflections: 7.03
• Weighted residual factors for significantly intense reflections: 7.03
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No