Information card for entry 1100577

Structure parameters

• Formula: C37 H95 N3 Na O9 Si7 Sm
• Calculated formula: C37 H95 N3 Na O9 Si7 Sm
• SMILES: C[Si](C)(C)N([Sm](N([Si](C)(C)C)[Si](C)(C)C)(N([Si](C)(C)C)[Si](C)(C)C)[O][Si](C)(C)C)[Si](C)(C)C.C1[O]2CC[O]3CC[O]4CC[O](C1)[Na]234156[O]2CC[O]1CC[O]5CC[O]6CC2
• Title of publication: Amidometallate von Seltenerdelementen. Synthese und Kristallstrukturen von [Na(12-Krone-4)~2~][M{N(SiMe~3~)~2~}~3~(OSiMe~3~)] (M = Sm, Yb), [Na(THF)~3~Sm{N(SiMe~3~)~2~}~3~(C≡C-Ph)], [Na(THF)~6~][Lu~2~(μ-NH~2~)(μ-NSiMe~3~){N(SiMe~3~)~2~}~4~] sowie von [NaN(SiMe~3~)~2~(THF)]~2~. Anwendungen der Seltenerdkomplexe als Polymerisationskatalysatoren
• Authors of publication: Karl, M.; Seybert, G.; Massa, W.; Harms, K.; Agarwal, S.; Maleika, R.; Stelter, W.; Greiner, A.; Neumüller, W.; Heitz, B.; Dehnicke, K.
• Journal of publication: Zeitschrift für anorganische und allgemeine Chemie
• Year of publication: 1999
• Journal volume: 625
• Journal issue: 8
• Pages of publication: 1301 - 1309
• a: 22.753 ± 0.002 Å
• b: 22.2736 ± 0.0014 Å
• c: 23.844 ± 0.002 Å
• α: 90°
• β: 94.925 ± 0.015°
• γ: 90°
• Cell volume: 12039.3 ų
• Number of distinct elements: 7
• Space group number: 15
• Hermann-Mauguin space group symbol: I 1 2/a 1
• Hall space group symbol: -I 2ya
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No