Information card for entry 1508074

Structure parameters

• Formula: C26 H48 N2 Si2 U
• Calculated formula: C26 H48 N2 Si2 U
• SMILES: [U]123456789(N([Si](C)(C)C)[Si](C)(C)C)(NC[c]%103[c]2([c]1([c]5([c]4%10C)C)C)C)[c]1([c]6([c]7([c]8([c]91C)C)C)C)C
• Title of publication: Uranium azide photolysis results in C-H bond activation and provides evidence for a terminal uranium nitride.
• Authors of publication: Thomson, Robert K.; Cantat, Thibault; Scott, Brian L.; Morris, David E.; Batista, Enrique R.; Kiplinger, Jaqueline L.
• Journal of publication: Nature chemistry
• Year of publication: 2010
• Journal volume: 2
• Journal issue: 9
• Pages of publication: 723 - 729
• a: 31.4069 ± 0.0019 Å
• b: 31.4069 ± 0.0019 Å
• c: 23.029 ± 0.003 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 22716 ± 4 ų
• Cell temperature: 140 ± 1 K
• Ambient diffraction temperature: 140 ± 1 K
• Number of distinct elements: 5
• Space group number: 88
• Hermann-Mauguin space group symbol: I 41/a :2
• Hall space group symbol: -I 4ad
• Residual factor for all reflections: 0.0478
• Residual factor for significantly intense reflections: 0.0294
• Weighted residual factors for significantly intense reflections: 0.067
• Weighted residual factors for all reflections included in the refinement: 0.0737
• Goodness-of-fit parameter for all reflections included in the refinement: 1.014
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No