Information card for entry 1516134

Structure parameters

• Formula: C19 H27 N O2 S Si
• Calculated formula: C19 H27 N O2 S Si
• SMILES: S(=O)(=O)(N[C@H]([Si](c1ccccc1)(C)C)c1ccccc1)C(C)(C)C
• Title of publication: Catalytic Enantioselective Silylation of N-Sulfonylimines: Asymmetric Synthesis of α-Amino Acids from CO2 via Stereospecific Carboxylation of α-Amino Silanes.
• Authors of publication: Mita, Tsuyoshi; Sugawara, Masumi; Saito, Keisuke; Sato, Yoshihiro
• Journal of publication: Organic letters
• Year of publication: 2014
• Journal volume: 16
• Journal issue: 11
• Pages of publication: 3028 - 3031
• a: 9.154 ± 0.003 Å
• b: 16.606 ± 0.005 Å
• c: 13.184 ± 0.004 Å
• α: 90°
• β: 91.919 ± 0.004°
• γ: 90°
• Cell volume: 2003 ± 1.1 ų
• Cell temperature: 93 K
• Ambient diffraction temperature: 93 K
• Number of distinct elements: 6
• Space group number: 4
• Hermann-Mauguin space group symbol: P 1 21 1
• Hall space group symbol: P 2yb
• Residual factor for significantly intense reflections: 0.026
• Weighted residual factors for all reflections included in the refinement: 0.0661
• Goodness-of-fit parameter for all reflections included in the refinement: 1.071
• Diffraction radiation wavelength: 0.71075 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No