Information card for entry 1532482

Structure parameters

• Formula: C49 H62 Cl Ge N Si
• Calculated formula: C49 H62 Cl Ge N Si
• SMILES: [GeH](Cl)(N([Si](C(C)C)(C(C)C)C(C)C)c1c(cc(cc1C(c1ccccc1)c1ccccc1)C(C)C)C(c1ccccc1)c1ccccc1)C1CCCC1
• Title of publication: Two-coordinate group 14 element(ii) hydrides as reagents for the facile, and sometimes reversible, hydrogermylation/hydrostannylation of unactivated alkenes and alkynes
• Authors of publication: Hadlington, Terrance J.; Hermann, Markus; Frenking, Gernot; Jones, Cameron
• Journal of publication: Chem. Sci.
• Year of publication: 2015
• Journal volume: 6
• Journal issue: 12
• Pages of publication: 7249
• a: 10.731 ± 0.002 Å
• b: 14.446 ± 0.003 Å
• c: 15.647 ± 0.003 Å
• α: 77.83 ± 0.03°
• β: 78.54 ± 0.03°
• γ: 69.06 ± 0.03°
• Cell volume: 2194.2 ± 0.9 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0741
• Residual factor for significantly intense reflections: 0.0635
• Weighted residual factors for significantly intense reflections: 0.1721
• Weighted residual factors for all reflections included in the refinement: 0.1805
• Goodness-of-fit parameter for all reflections included in the refinement: 1.043
• Diffraction radiation wavelength: 0.7109 Å
• Diffraction radiation type: Synchrotron
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No