Information card for entry 1532483

Structure parameters

• Formula: C48 H63 Ge N O Si
• Calculated formula: C48 H63 Ge N O Si
• SMILES: [GeH](OCC)(N([Si](C(C)C)(C(C)C)C(C)C)c1c(cc(cc1C(c1ccccc1)c1ccccc1)C(C)C)C(c1ccccc1)c1ccccc1)CC
• Title of publication: Two-coordinate group 14 element(ii) hydrides as reagents for the facile, and sometimes reversible, hydrogermylation/hydrostannylation of unactivated alkenes and alkynes
• Authors of publication: Hadlington, Terrance J.; Hermann, Markus; Frenking, Gernot; Jones, Cameron
• Journal of publication: Chem. Sci.
• Year of publication: 2015
• Journal volume: 6
• Journal issue: 12
• Pages of publication: 7249
• a: 10.399 ± 0.0004 Å
• b: 14.2109 ± 0.0005 Å
• c: 15.4524 ± 0.0005 Å
• α: 90.483 ± 0.001°
• β: 101.026 ± 0.001°
• γ: 105.118 ± 0.001°
• Cell volume: 2159.72 ± 0.13 ų
• Cell temperature: 123 ± 2 K
• Ambient diffraction temperature: 123 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0617
• Residual factor for significantly intense reflections: 0.044
• Weighted residual factors for significantly intense reflections: 0.1047
• Weighted residual factors for all reflections included in the refinement: 0.1127
• Goodness-of-fit parameter for all reflections included in the refinement: 1.049
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No