Information card for entry 1552515

Structure parameters

• Formula: C25 H59 Mn N2 P4 Si
• Calculated formula: C25 H59 Mn N2 P4 Si
• SMILES: c1(n(C(C)C)cc[n+]1C(C)C)[SiH](CCCC)[MnH]12([P](C)(CC[P]1(C)C)C)[P](C)(C)CC[P]2(C)C
• Title of publication: Interconversion and reactivity of manganese silyl, silylene, and silene complexes
• Authors of publication: Price, Jeffrey S.; Emslie, David J. H.
• Journal of publication: Chemical Science
• Year of publication: 2019
• a: 10.279 ± 0.002 Å
• b: 12.666 ± 0.003 Å
• c: 13.295 ± 0.003 Å
• α: 70.86 ± 0.03°
• β: 84.97 ± 0.03°
• γ: 87.74 ± 0.03°
• Cell volume: 1628.8 ± 0.7 ų
• Cell temperature: 100 K
• Ambient diffraction temperature: 100 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1071
• Residual factor for significantly intense reflections: 0.0363
• Weighted residual factors for significantly intense reflections: 0.0407
• Weighted residual factors for all reflections included in the refinement: 0.0511
• Goodness-of-fit parameter for all reflections included in the refinement: 0.59
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No