Information card for entry 1552516

Structure parameters

• Formula: C23 H48 Mn N P4 Si
• Calculated formula: C23 H48 Mn N P4 Si
• SMILES: c1(ccccc1)[SiH2][Mn]12([P](C)(C)CC[P]1(C)C)([P](C)(C)CC[P]2(C)C)C#[N]C(C)(C)C
• Title of publication: Interconversion and reactivity of manganese silyl, silylene, and silene complexes
• Authors of publication: Price, Jeffrey S.; Emslie, David J. H.
• Journal of publication: Chemical Science
• Year of publication: 2019
• a: 12.3626 ± 0.0003 Å
• b: 14.0448 ± 0.0003 Å
• c: 17.4117 ± 0.0004 Å
• α: 89.648 ± 0.001°
• β: 74.86 ± 0.001°
• γ: 89.884 ± 0.001°
• Cell volume: 2918.21 ± 0.12 ų
• Cell temperature: 100 K
• Ambient diffraction temperature: 100 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0591
• Residual factor for significantly intense reflections: 0.0519
• Weighted residual factors for significantly intense reflections: 0.1119
• Weighted residual factors for all reflections included in the refinement: 0.1139
• Goodness-of-fit parameter for all reflections included in the refinement: 1.252
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No