Information card for entry 1552518

Structure parameters

• Formula: C27 H55 Mn N2 P4 Si
• Calculated formula: C26.988 H54.968 Mn N2 P3.996 Si
• SMILES: c1([n+](ccn1C(C)C)C(C)C)[SiH](c1ccccc1)[MnH]12([P](C)(C)CC[P]1(C)C)[P](C)(C)CC[P]2(C)C
• Title of publication: Interconversion and reactivity of manganese silyl, silylene, and silene complexes
• Authors of publication: Price, Jeffrey S.; Emslie, David J. H.
• Journal of publication: Chemical Science
• Year of publication: 2019
• a: 30.089 ± 0.003 Å
• b: 12.8432 ± 0.0011 Å
• c: 17.3407 ± 0.0015 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 6701.1 ± 1.1 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 K
• Number of distinct elements: 6
• Space group number: 56
• Hermann-Mauguin space group symbol: P c c n
• Hall space group symbol: -P 2ab 2ac
• Residual factor for all reflections: 0.1543
• Residual factor for significantly intense reflections: 0.103
• Weighted residual factors for significantly intense reflections: 0.2048
• Weighted residual factors for all reflections included in the refinement: 0.2289
• Goodness-of-fit parameter for all reflections included in the refinement: 1.208
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No