Information card for entry 1552517

Structure parameters

• Formula: C25 H51 Mn N2 P4 Si
• Calculated formula: C25 H51 Mn N2 P4 Si
• SMILES: [MnH]12([P](C)(C)CC[P]1(C)C)([P](C)(C)CC[P]2(C)C)[SiH](=C1N(C(=C(N1C)C)C)C)c1ccccc1
• Title of publication: Interconversion and reactivity of manganese silyl, silylene, and silene complexes
• Authors of publication: Price, Jeffrey S.; Emslie, David J. H.
• Journal of publication: Chemical Science
• Year of publication: 2019
• a: 9.637 ± 0.0019 Å
• b: 10.491 ± 0.002 Å
• c: 16.231 ± 0.003 Å
• α: 80.96 ± 0.03°
• β: 75.69 ± 0.03°
• γ: 81.08 ± 0.03°
• Cell volume: 1558.7 ± 0.6 ų
• Cell temperature: 100 K
• Ambient diffraction temperature: 100 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.102
• Residual factor for significantly intense reflections: 0.0459
• Weighted residual factors for significantly intense reflections: 0.0806
• Weighted residual factors for all reflections included in the refinement: 0.0881
• Goodness-of-fit parameter for all reflections included in the refinement: 0.816
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No