Information card for entry 1556169

Structure parameters

• Formula: C12 H20 N2 O Si
• Calculated formula: C12 H20 N2 O Si
• SMILES: [Si](O[C@H]1[C@H]2N=N[C@@H]3[C@H]2[C@@H]2[C@H]1C[C@H]3C2)(C)(C)C
• Title of publication: Sequential reactions of trimethylsilyldiazomethane with 4-alkenyl ketones and aldehydes catalyzed by Lewis bases.
• Authors of publication: Liu, Huaqing; O'Connor, Matthew J; Sun, Chunrui; Wink, Donald J.; Lee, Daesung
• Journal of publication: Organic letters
• Year of publication: 2013
• Journal volume: 15
• Journal issue: 12
• Pages of publication: 2974 - 2977
• a: 6.1243 ± 0.0013 Å
• b: 7.9668 ± 0.0017 Å
• c: 12.884 ± 0.003 Å
• α: 90°
• β: 98.931 ± 0.003°
• γ: 90°
• Cell volume: 621 ± 0.2 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 5
• Space group number: 4
• Hermann-Mauguin space group symbol: P 1 21 1
• Hall space group symbol: P 2yb
• Residual factor for all reflections: 0.0444
• Residual factor for significantly intense reflections: 0.0344
• Weighted residual factors for significantly intense reflections: 0.0969
• Weighted residual factors for all reflections included in the refinement: 0.1059
• Goodness-of-fit parameter for all reflections included in the refinement: 0.803
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No