Information card for entry 1560850

Structure parameters

• Formula: C31 H43 Br Ge N P Si
• Calculated formula: C31 H43 Br Ge N P Si
• SMILES: [Ge]1(Br)[P](c2ccccc2)(c2ccccc2)C[Si](N1c1c(C(C)C)cccc1C(C)C)(C(C)C)C(C)C
• Title of publication: Reversible metathesis of ammonia in an acyclic germylene‒Ni0 complex
• Authors of publication: Keil, Philip M.; Szilvási, Tibor; Hadlington, Terrance J.
• Journal of publication: Chemical Science
• Year of publication: 2021
• Journal volume: 12
• Journal issue: 15
• Pages of publication: 5582 - 5590
• a: 11.11 ± 0.002 Å
• b: 17.26 ± 0.004 Å
• c: 18.29 ± 0.004 Å
• α: 65.1 ± 0.03°
• β: 88.4 ± 0.03°
• γ: 85.3 ± 0.03°
• Cell volume: 3170.5 ± 1.4 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0804
• Residual factor for significantly intense reflections: 0.0609
• Weighted residual factors for significantly intense reflections: 0.1787
• Weighted residual factors for all reflections included in the refinement: 0.1968
• Goodness-of-fit parameter for all reflections included in the refinement: 1.057
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No