Syntheses, homeomorphic and configurational isomerizations, and structures of macrocyclic aliphatic dibridgehead diphosphines; molecules that turn themselves inside out
Authors of publication
Zhu, Yun; Stollenz, Michael; Zarcone, Samuel R.; Kharel, Sugam; Joshi, Hemant; Bhuvanesh, Nattamai; Reibenspies, Joseph H.; Gladysz, John A.
Journal of publication
Chemical Science
Year of publication
2022
a
45.099 ± 0.002 Å
b
12.6445 ± 0.0007 Å
c
9.399 ± 0.0005 Å
α
90°
β
96.694 ± 0.002°
γ
90°
Cell volume
5323.3 ± 0.5 Å3
Cell temperature
100 K
Ambient diffraction temperature
100 K
Number of distinct elements
3
Space group number
15
Hermann-Mauguin space group symbol
C 1 2/c 1
Hall space group symbol
-C 2yc
Residual factor for all reflections
0.0741
Residual factor for significantly intense reflections
0.0604
Weighted residual factors for significantly intense reflections
0.1447
Weighted residual factors for all reflections included in the refinement
0.1557
Goodness-of-fit parameter for all reflections included in the refinement
