Information card for entry 1568653

Structure parameters

• Formula: C107.5 H118 I2 N4 O2 P6 Rh2
• Calculated formula: C107.5 H118 I2 N4 O2 P6 Rh2
• Title of publication: Probing the donor strength of yldiide ligands: synthesis, structure and reactivity of rhodium complexes with a PC_ylideN pincer ligand.
• Authors of publication: Lapointe, Sébastien; Duari, Prakash; Gessner, Viktoria H.
• Journal of publication: Chemical science
• Year of publication: 2023
• Journal volume: 14
• Journal issue: 14
• Pages of publication: 3816 - 3825
• a: 17.9895 ± 0.0001 Å
• b: 19.0756 ± 0.0001 Å
• c: 19.2191 ± 0.0001 Å
• α: 89.783 ± 0.001°
• β: 67.234 ± 0.001°
• γ: 62.295 ± 0.001°
• Cell volume: 5257.42 ± 0.1 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0381
• Residual factor for significantly intense reflections: 0.0367
• Weighted residual factors for significantly intense reflections: 0.0889
• Weighted residual factors for all reflections included in the refinement: 0.0899
• Goodness-of-fit parameter for all reflections included in the refinement: 1.037
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No