Information card for entry 1574268

Structure parameters

• Formula: C99 H118 B Cl Ge2 O
• Calculated formula: C99 H118 B Cl Ge2 O
• Title of publication: Boradigermaallyl: inhibition of CH bond activation by borane CO adduct formation followed by CO insertion
• Authors of publication: Kern, Ralf H.; Hiller, Noemi; Eichele, Klaus; Schubert, Hartmut; Tönshoff, Christina; Bettinger, Holger F.; Wesemann, Lars
• Journal of publication: Chemical Science
• Year of publication: 2025
• Journal volume: 16
• Journal issue: 18
• Pages of publication: 7759 - 7765
• a: 15.9892 ± 0.0003 Å
• b: 19.2578 ± 0.0003 Å
• c: 20.5718 ± 0.0004 Å
• α: 102.631 ± 0.001°
• β: 112.298 ± 0.001°
• γ: 106.577 ± 0.001°
• Cell volume: 5221.48 ± 0.18 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0632
• Residual factor for significantly intense reflections: 0.0487
• Weighted residual factors for significantly intense reflections: 0.129
• Weighted residual factors for all reflections included in the refinement: 0.1407
• Goodness-of-fit parameter for all reflections included in the refinement: 1.047
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No