Information card for entry 2005087

Structure parameters

• Common name: lithium isodicyclopentadienide tetramethylethylenediamine
• Chemical name: (N,N,N',N'‒tetramethylethylenediamine)lithium(1+) (1,2,3,3a,7a‒η)‒4,5,6,7‒tetrahydro‒4,7‒methanoindenide
• Formula: C16 H27 Li N2
• Calculated formula: C16 H27 Li N2
• Title of publication: Two Derivatives of Lithium Isodicyclopentadienide: [(1,2,3,3a,7a-η)-4,5,6,7-Tetrahydro-4,7-methanoindenido](<i>N</i>,<i>N</i>,<i>N</i>',<i>N</i>'-tetramethylethylenediamine)lithium and Bis(1,4,7,10-tetraoxacyclododecane)lithium(1+) Bis[(1,2,3,3a,7a-η)-4,5,6,7-tetrahydro-4,7-methanoindenido]lithate(1‒)
• Authors of publication: Gallucci, J. C.; Sivik, M. R.; Paquette, L. A.; Zaegel, F.; Meunier, P.; Gautheron, B.
• Journal of publication: Acta Crystallographica Section C
• Year of publication: 1996
• Journal volume: 52
• Journal issue: 7
• Pages of publication: 1673 - 1679
• a: 8.216 ± 0.002 Å
• b: 16.164 ± 0.002 Å
• c: 12.762 ± 0.002 Å
• α: 90°
• β: 107.12 ± 0.02°
• γ: 90°
• Cell volume: 1619.7 ± 0.5 ų
• Cell temperature: 296 K
• Ambient diffraction temperature: 296 K
• Number of distinct elements: 4
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.2548
• Residual factor for significantly intense reflections: 0.059
• Weighted residual factors for all reflections: 0.189
• Weighted residual factors for significantly intense reflections: 0.125
• Goodness-of-fit parameter for all reflections: 1
• Goodness-of-fit parameter for significantly intense reflections: 1.253
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No