Information card for entry 2010039

Structure parameters

• Chemical name: bis(diazabicyclo[4.3.0]non-5-ene)(cycloocta-1,5-diene)rhodium(I)hexa- fluorophosphate
• Formula: C22 H36 F6 N4 P Rh
• Calculated formula: C22 H36 F6 N4 P Rh
• Title of publication: Rhodium(I) complexes with 1,5-diazabicyclo[4.3.0]non-5-ene (dbn) as a ligand: [RhCl(nbd)(dbn)] (I) and [Rh(dbn)~2~(cod)][PF~6~] (II) (nbd = norbornadiene, cod = 1,5-cyclooctadiene)
• Authors of publication: Flörke, Ulrich; Haupt, Hans-Jürgen
• Journal of publication: Acta Crystallographica Section C
• Year of publication: 1994
• Journal volume: 50
• Journal issue: 9
• Pages of publication: 1424 - 1427
• a: 18.245 ± 0.003 Å
• b: 8.333 ± 0.001 Å
• c: 16.535 ± 0.003 Å
• α: 90°
• β: 94.92 ± 0.01°
• γ: 90°
• Cell volume: 2504.6 ± 0.7 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 6
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0416
• Residual factor for significantly intense reflections: 0.0347
• Weighted residual factors for all reflections: 0.0967
• Weighted residual factors for significantly intense reflections: 0.0904
• Goodness-of-fit parameter for all reflections: 1.037
• Goodness-of-fit parameter for significantly intense reflections: 1.046
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No