Information card for entry 2012965

Structure parameters

• Chemical name: Bis(2,2'-bipyridine-κ^2^N,N')(dicyanamido-κN')copper(II) perchlorate
• Formula: C22 H16 Cl Cu N7 O4
• Calculated formula: C22 H16 Cl Cu N7 O4
• SMILES: Cl(=O)(=O)(=O)[O-].[Cu]12([N]#C[N-]C#N)([n]3c(cccc3)c3[n]1cccc3)[n]1c(cccc1)c1[n]2cccc1
• Title of publication: Low-dimensional compounds containing cyano groups. IV. Bis(2,2'-bipyridine-κ^2^<i>N</i>,<i>N</i>^1^)(dicyanamido-κ<i>N</i>')copper(II) perchlorate and μ-dicyanamido-κ^2^<i>N</i>^1^:<i>N</i>^5^-bis[bis(2,2'-bipyridine-κ^2^<i>N</i>,<i>N</i>')copper(II)] triperchlorate ethanol hemisolvate, complexes with unusual dicyanamide coordination
• Authors of publication: Potočňák, Ivan; Burčák, Milan; Massa, Werner; Jäger, Lothar
• Journal of publication: Acta Crystallographica Section C
• Year of publication: 2002
• Journal volume: 58
• Journal issue: 10
• Pages of publication: m523 - m528
• a: 8.7343 ± 0.0004 Å
• b: 17.945 ± 0.0009 Å
• c: 28.723 ± 0.0017 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 4502 ± 0.4 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 6
• Space group number: 61
• Hermann-Mauguin space group symbol: P b c a
• Hall space group symbol: -P 2ac 2ab
• Residual factor for all reflections: 0.064
• Residual factor for significantly intense reflections: 0.036
• Weighted residual factors for significantly intense reflections: 0.084
• Weighted residual factors for all reflections included in the refinement: 0.091
• Goodness-of-fit parameter for all reflections included in the refinement: 0.969
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: Yes