Information card for entry 2012966

Structure parameters

• Chemical name: μ-dicyanamido-κ^2^N^1^:N^3^-bis[bis(2,2'-bipyridine-κ^2^N,N')copper(II)] tris(perchlorate) ethanol hemisolvate
• Formula: C43 H35 Cl3 Cu2 N11 O12.5
• Calculated formula: C43 H35 Cl3 Cu2 N11 O12.5
• Title of publication: Low-dimensional compounds containing cyano groups. IV. Bis(2,2'-bipyridine-κ^2^<i>N</i>,<i>N</i>^1^)(dicyanamido-κ<i>N</i>')copper(II) perchlorate and μ-dicyanamido-κ^2^<i>N</i>^1^:<i>N</i>^5^-bis[bis(2,2'-bipyridine-κ^2^<i>N</i>,<i>N</i>')copper(II)] triperchlorate ethanol hemisolvate, complexes with unusual dicyanamide coordination
• Authors of publication: Potočňák, Ivan; Burčák, Milan; Massa, Werner; Jäger, Lothar
• Journal of publication: Acta Crystallographica Section C
• Year of publication: 2002
• Journal volume: 58
• Journal issue: 10
• Pages of publication: m523 - m528
• a: 10.2999 ± 0.0009 Å
• b: 14.3808 ± 0.0012 Å
• c: 16.4311 ± 0.0016 Å
• α: 74.12 ± 0.01°
• β: 83.371 ± 0.011°
• γ: 80.046 ± 0.01°
• Cell volume: 2299.7 ± 0.4 ų
• Cell temperature: 193 ± 2 K
• Ambient diffraction temperature: 193 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.104
• Residual factor for significantly intense reflections: 0.046
• Weighted residual factors for significantly intense reflections: 0.099
• Weighted residual factors for all reflections included in the refinement: 0.113
• Goodness-of-fit parameter for all reflections included in the refinement: 0.837
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: Yes