Information card for entry 2019448

Structure parameters

• Chemical name: bis{μ-<i>N</i>-[(diphenylphosphanyl)methyl]pyridin-4-amine-κ^2^<i>N</i>^1^:<i>P</i>}bis[(nitrato-κ^2^<i>O</i>,<i>O</i>)silver]
• Formula: C36 H34 Ag2 N6 O6 P2
• Calculated formula: C36 H34 Ag2 N6 O6 P2
• SMILES: c12cc[n](cc2)[Ag][P](CNc2cc[n]([Ag][P](CN1)(c1ccccc1)c1ccccc1)cc2)(c1ccccc1)c1ccccc1.N(=O)(=O)[O-].N(=O)(=O)[O-]
• Title of publication: Counter-anion role in the formation of two supramolecular complexes: [Ag~2~(DPP)~2~](ClO~4~)~2~·CH~3~CN and [Ag~2~(DPP)~2~(NO~3~)~2~] {DPP is <i>N</i>-[(diphenylphosphanyl)methyl]pyridin-4-amine}
• Authors of publication: Liang, Guang-Ming; Shang, Jing; Yang, Kun-Guo; Ma, Kai; Ni, Qing-Ling
• Journal of publication: Acta Crystallographica Section C
• Year of publication: 2014
• Journal volume: 70
• Journal issue: 4
• Pages of publication: 379 - 383
• a: 13.448 ± 0.005 Å
• b: 17.498 ± 0.006 Å
• c: 16.006 ± 0.005 Å
• α: 90°
• β: 97.475 ± 0.004°
• γ: 90°
• Cell volume: 3734 ± 2 ų
• Cell temperature: 296 ± 2 K
• Ambient diffraction temperature: 296 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0439
• Residual factor for significantly intense reflections: 0.0298
• Weighted residual factors for significantly intense reflections: 0.0729
• Weighted residual factors for all reflections included in the refinement: 0.0805
• Goodness-of-fit parameter for all reflections included in the refinement: 1.023
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: Yes