Information card for entry 2020677

Structure parameters

• Chemical name: Bis{μ-2-[(2,6-diisopropylphenyl)iminomethyl]phenolato}-κ^3^<i>N</i>,<i>O</i>:<i>O</i>;κ^3^<i>O</i>:<i>N</i>,<i>O</i>-bis[(hexamethyldisilazido-κ<i>N</i>)magnesium(II)]
• Formula: C50 H80 Mg2 N4 O2 Si4
• Calculated formula: C50 H80 Mg2 N4 O2 Si4
• SMILES: N([Mg]12[O](c3ccccc3C=[N]2c2c(cccc2C(C)C)C(C)C)[Mg]2(N([Si](C)(C)C)[Si](C)(C)C)[O]1c1ccccc1C=[N]2c1c(cccc1C(C)C)C(C)C)([Si](C)(C)C)[Si](C)(C)C
• Title of publication: Solvent dependence of the solid-state structures of salicylaldiminate magnesium amide complexes
• Authors of publication: Rood, Jeffrey A.; Landis, Ashley M.; Forster, Daniel R.; Goldkamp, Timothy; Oliver, Allen G.
• Journal of publication: Acta Crystallographica Section C
• Year of publication: 2016
• Journal volume: 72
• Journal issue: 12
• Pages of publication: 990 - 996
• a: 10.4898 ± 0.0011 Å
• b: 11.3067 ± 0.0012 Å
• c: 12.737 ± 0.0013 Å
• α: 76.033 ± 0.001°
• β: 66.454 ± 0.001°
• γ: 81.772 ± 0.001°
• Cell volume: 1342.1 ± 0.2 ų
• Cell temperature: 120 ± 2 K
• Ambient diffraction temperature: 120 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.035
• Residual factor for significantly intense reflections: 0.0306
• Weighted residual factors for significantly intense reflections: 0.0997
• Weighted residual factors for all reflections included in the refinement: 0.1026
• Goodness-of-fit parameter for all reflections included in the refinement: 1.588
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: Yes