Information card for entry 2243144

Structure parameters

• Chemical name: Bis[bis(1,3-dibenzyl-4,5-diphenylimidazol-2-ylidene)silver(I)] tris(thiocyanato)argentate(I) diethyl ether disolvate
• Formula: C127 H116 Ag3 N11 O2 S3
• Calculated formula: C123 H106 Ag3 N11 O S3
• Title of publication: Unexpected reactions of NHC*—Cu^I^ and —Ag^I^ bromides with potassium thio- or selenocyanate
• Authors of publication: Tacke, Matthias; Marhöfer, Daniel; Althani, Hessah; Müller-Bunz, Helge
• Journal of publication: Acta Crystallographica Section E
• Year of publication: 2019
• Journal volume: 75
• Journal issue: 11
• Pages of publication: 1657 - 1663
• a: 14.86462 ± 0.00008 Å
• b: 19.3714 ± 0.0001 Å
• c: 19.85451 ± 0.00009 Å
• α: 102.771 ± 0.0004°
• β: 100.827 ± 0.0004°
• γ: 99.5778 ± 0.0004°
• Cell volume: 5345.84 ± 0.05 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0368
• Residual factor for significantly intense reflections: 0.0298
• Weighted residual factors for significantly intense reflections: 0.0759
• Weighted residual factors for all reflections included in the refinement: 0.0803
• Goodness-of-fit parameter for all reflections included in the refinement: 1.027
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: Yes