Information card for entry 2243145

Structure parameters

• Chemical name: Bis(μ-1,3-dibenzyl-4,5-diphenyl-2-selenoimidazole-κ^2^<i>Se</i>:<i>Se</i>)bis[bromido(1,3-dibenzyl-4,5-diphenyl-2-selenoimidazole-κ<i>Se</i>)silver(I)] dichloromethane hexasolvate
• Formula: C122 H108 Ag2 Br2 Cl12 N8 Se4
• Calculated formula: C120 H104 Ag2 Br2 Cl8 N8 Se4
• Title of publication: Unexpected reactions of NHC*—Cu^I^ and —Ag^I^ bromides with potassium thio- or selenocyanate
• Authors of publication: Tacke, Matthias; Marhöfer, Daniel; Althani, Hessah; Müller-Bunz, Helge
• Journal of publication: Acta Crystallographica Section E
• Year of publication: 2019
• Journal volume: 75
• Journal issue: 11
• Pages of publication: 1657 - 1663
• a: 13.6265 ± 0.0001 Å
• b: 14.7422 ± 0.0001 Å
• c: 16.9397 ± 0.0002 Å
• α: 106.417 ± 0.0007°
• β: 112.282 ± 0.0008°
• γ: 96.2211 ± 0.0006°
• Cell volume: 2930.05 ± 0.05 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0406
• Residual factor for significantly intense reflections: 0.0348
• Weighted residual factors for significantly intense reflections: 0.0915
• Weighted residual factors for all reflections included in the refinement: 0.0959
• Goodness-of-fit parameter for all reflections included in the refinement: 1.031
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: Yes