Crystallography Open Database

Information card for entry 4023280

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Coordinates	4023280.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C25 H22 N2 O8
Calculated formula	C25 H22 N2 O8
Title of publication	Rh-Catalyzed Formation of Dioxolanes from α-Alkyl Diazoesters: Diastereoselective Cycloadditions of Carbonyl Ylides with Selectivity over β-Hydride Elimination
Authors of publication	Andrew DeAngelis; Patricia Panne; Glenn P. A. Yap; Joseph M. Fox
Journal of publication	Journal of Organic Chemistry
Year of publication	2008
Journal volume	73
Pages of publication	1435 - 1439
a	17.477 ± 0.011 Å
b	12.592 ± 0.007 Å
c	11.07 ± 0.007 Å
α	90°
β	103.58 ± 0.009°
γ	90°
Cell volume	2368 ± 2 Å³
Cell temperature	230 ± 2 K
Ambient diffraction temperature	230 ± 2 K
Number of distinct elements	4
Space group number	14
Hermann-Mauguin space group symbol	P 1 21/c 1
Hall space group symbol	-P 2ybc
Residual factor for all reflections	0.0721
Residual factor for significantly intense reflections	0.0562
Weighted residual factors for significantly intense reflections	0.2108
Weighted residual factors for all reflections included in the refinement	0.2464
Goodness-of-fit parameter for all reflections included in the refinement	1.049
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	Yes
Has F_obs	No

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