Crystallography Open Database

Information card for entry 4023282

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Coordinates	4023282.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C33 H28 O4
Calculated formula	C33 H28 O4
Title of publication	Rh-Catalyzed Formation of Dioxolanes from α-Alkyl Diazoesters: Diastereoselective Cycloadditions of Carbonyl Ylides with Selectivity over β-Hydride Elimination
Authors of publication	Andrew DeAngelis; Patricia Panne; Glenn P. A. Yap; Joseph M. Fox
Journal of publication	Journal of Organic Chemistry
Year of publication	2008
Journal volume	73
Pages of publication	1435 - 1439
a	10.876 ± 0.004 Å
b	11.998 ± 0.004 Å
c	21.376 ± 0.007 Å
α	95.456 ± 0.006°
β	103.74 ± 0.005°
γ	106.053 ± 0.006°
Cell volume	2565.1 ± 1.4 Å³
Cell temperature	160 ± 2 K
Ambient diffraction temperature	160 ± 2 K
Number of distinct elements	3
Space group number	2
Hermann-Mauguin space group symbol	P -1
Hall space group symbol	-P 1
Residual factor for all reflections	0.124
Residual factor for significantly intense reflections	0.0869
Weighted residual factors for significantly intense reflections	0.2979
Weighted residual factors for all reflections included in the refinement	0.369
Goodness-of-fit parameter for all reflections included in the refinement	1.025
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	Yes
Has F_obs	No

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