Information card for entry 4030339

Structure parameters

• Formula: C20 H30 Br4 Li O4 P2 W
• Calculated formula: C20 Br4 Li O4 P2 W
• SMILES: [W](Br)(Br)(Br)(Br)([O]=P(C)(C)c1ccccc1)=[O][Li]1([O]2CCCC2)[O](=P(C)(C)c2ccccc2)[Li]([O]2CCCC2)([O]1=P(C)(C)c1ccccc1)[O]=[W](Br)(Br)(Br)(Br)[O]=P(C)(C)c1ccccc1
• Title of publication: Oxohalo complexes of W (V) and W (IV). The synthesis od crystal structures of [WOCl (dppe)2][BPh4], [PHMe2Ph][WOBr4(OPMe2Ph)] and [Li(OPMe2Ph)(THF)]2[WOBr4(OPMe2Ph)]2
• Authors of publication: Cotton, F. A.; Mandal, S. K.
• Journal of publication: European Journal of Solid State and Inorganic Chemistry
• Year of publication: 1991
• Journal volume: 28
• Pages of publication: 775 - 797
• a: 14.461 ± 0.005 Å
• b: 10.199 ± 0.002 Å
• c: 19.767 ± 0.009 Å
• α: 90°
• β: 90.94 ± 0.01°
• γ: 90°
• Cell volume: 2915 ± 1.8 ų
• Ambient diffraction temperature: 294 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for significantly intense reflections: 0.046
• Weighted residual factors for significantly intense reflections: 0.066
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71069 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No