Information card for entry 4030338

Structure parameters

• Formula: C16 H23 Br4 O2 P2 W
• Calculated formula: C16 Br4 O2 P2 W
• SMILES: [W](Br)(Br)(Br)(Br)([O]=P(c1ccccc1)(C)C)=O.P(c1ccccc1)(C)C
• Title of publication: Oxohalo complexes of W (V) and W (IV). The synthesis od crystal structures of [WOCl (dppe)2][BPh4], [PHMe2Ph][WOBr4(OPMe2Ph)] and [Li(OPMe2Ph)(THF)]2[WOBr4(OPMe2Ph)]2
• Authors of publication: Cotton, F. A.; Mandal, S. K.
• Journal of publication: European Journal of Solid State and Inorganic Chemistry
• Year of publication: 1991
• Journal volume: 28
• Pages of publication: 775 - 797
• a: 13.169 ± 0.004 Å
• b: 13.059 ± 0.006 Å
• c: 28.222 ± 0.011 Å
• α: 90°
• β: 100.2 ± 0.03°
• γ: 90°
• Cell volume: 4777 ± 3 ų
• Ambient diffraction temperature: 294 K
• Number of distinct elements: 6
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for significantly intense reflections: 0.074
• Weighted residual factors for significantly intense reflections: 0.092
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71069 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No