Information card for entry 4060078

Structure parameters

• Chemical name: (pentamethylcyclopentadienyl)(triisopropylphosphine) (methyldichlorosilyl)ruthenium dihydride
• Formula: C20 H41 Cl2 P Ru Si
• Calculated formula: C20 H41 Cl2 P Ru Si
• Title of publication: Syntheses and X-ray Diffraction Studies of Half-Sandwich Hydridosilyl Complexes of Ruthenium
• Authors of publication: Osipov, Alexander L.; Gerdov, Sergei M.; Kuz'mina, Lyudmila G.; Howard, Judith A. K.; Nikonov, Georgii I.
• Journal of publication: Organometallics
• Year of publication: 2005
• Journal volume: 24
• Journal issue: 4
• Pages of publication: 587 - 602
• a: 13.8023 ± 0.0008 Å
• b: 9.8582 ± 0.0005 Å
• c: 17.8192 ± 0.001 Å
• α: 90°
• β: 94.1 ± 0.002°
• γ: 90°
• Cell volume: 2418.4 ± 0.2 ų
• Cell temperature: 123 ± 2 K
• Ambient diffraction temperature: 123 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0291
• Residual factor for significantly intense reflections: 0.0265
• Weighted residual factors for significantly intense reflections: 0.0734
• Weighted residual factors for all reflections included in the refinement: 0.0748
• Goodness-of-fit parameter for all reflections included in the refinement: 1.067
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No