Information card for entry 4062576

Structure parameters

• Formula: C18 H32 O12 Rh2 S2
• Calculated formula: C18 H32 O12 Rh2 S2
• SMILES: [S](C)(CC(=O)OCC)[Rh]1234[O]=C(C)O[Rh]4([S](C)CC(=O)OCC)([O]=C(C)O1)(OC(C)=[O]3)[O]=C(C)O2
• Title of publication: Cationic Carboxylato Complexes of Dirhodium(II) with Oxo Thioethers: Promising Catalysts with Unusual Coordination Modes
• Authors of publication: Basato, Marino; Biffis, Andrea; Martinati, Gianluca; Zecca, Marco; Ganis, Paolo; Benetollo, Franco; Aronica, Laura A.; Caporusso, Anna M.
• Journal of publication: Organometallics
• Year of publication: 2004
• Journal volume: 23
• Journal issue: 8
• Pages of publication: 1947 - 1952
• a: 17.622 ± 0.003 Å
• b: 8.535 ± 0.002 Å
• c: 18.667 ± 0.003 Å
• α: 90°
• β: 106.32 ± 0.02°
• γ: 90°
• Cell volume: 2694.5 ± 0.9 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 5
• Space group number: 15
• Hermann-Mauguin space group symbol: I 1 2/a 1
• Hall space group symbol: -I 2ya
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No