Information card for entry 4062577

Structure parameters

• Formula: C16 H29.5 B F4 O10.25 Rh2 S2
• Calculated formula: C16 H29 B F4 O10.25 Rh2 S2
• SMILES: [Rh]1234([Rh]5([S](C)CC(=[O]5)OCC)(OC(=[O]1)C)([O]=C(O2)C)[O]=C(O3)C)[S](C)CC(=[O]4)OCC.[B](F)(F)(F)[F-].O
• Title of publication: Cationic Carboxylato Complexes of Dirhodium(II) with Oxo Thioethers: Promising Catalysts with Unusual Coordination Modes
• Authors of publication: Basato, Marino; Biffis, Andrea; Martinati, Gianluca; Zecca, Marco; Ganis, Paolo; Benetollo, Franco; Aronica, Laura A.; Caporusso, Anna M.
• Journal of publication: Organometallics
• Year of publication: 2004
• Journal volume: 23
• Journal issue: 8
• Pages of publication: 1947 - 1952
• a: 30.225 ± 0.005 Å
• b: 14.103 ± 0.003 Å
• c: 13.148 ± 0.003 Å
• α: 90°
• β: 93.08 ± 0.03°
• γ: 90°
• Cell volume: 5596 ± 2 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 7
• Space group number: 5
• Hermann-Mauguin space group symbol: C 1 2 1
• Hall space group symbol: C 2y
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No