Information card for entry 4063231

Structure parameters

• Common name: [{MgCl(MesNPPh2CHPPh2NMes)}2].2(toluene)
• Formula: C100 H102 Cl2 Mg2 N4 P4
• Calculated formula: C100 H102 Cl2 Mg2 N4 P4
• Title of publication: Synthesis and M-Cγ Hemilability of Group 2 Bis(phosphinimino)methanides
• Authors of publication: Shabana A. Ahmed; Michael S. Hill; Peter B. Hitchcock
• Journal of publication: Organometallics
• Year of publication: 2006
• Journal volume: 25
• Journal issue: 2
• Pages of publication: 394 - 402
• a: 12.0127 ± 0.0003 Å
• b: 11.8443 ± 0.0003 Å
• c: 30.8127 ± 0.0008 Å
• α: 90°
• β: 96.916 ± 0.001°
• γ: 90°
• Cell volume: 4352.2 ± 0.2 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0755
• Residual factor for significantly intense reflections: 0.0508
• Weighted residual factors for significantly intense reflections: 0.1052
• Weighted residual factors for all reflections included in the refinement: 0.1148
• Goodness-of-fit parameter for all reflections included in the refinement: 1.058
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No