Information card for entry 4063613

Structure parameters

• Common name: 10a
• Chemical name: [N-(dimethylamino)benzimidato-N',O]hydridophenylsilicon(IV)
• Formula: C24 H28 N4 O2 Si
• Calculated formula: C24 H28 N4 O2 Si
• SMILES: [SiH]12([N](N=C(O1)c1ccccc1)(C)C)([N](N=C(O2)c1ccccc1)(C)C)c1ccccc1
• Title of publication: Reversible Neutral Dissociation of the N‒Si Dative Bond in Hexacoordinate Hydrido Complexes of Silicon
• Authors of publication: Kalikhman, Inna; Kertsnus-Banchik, Evgenia; Gostevskii, Boris; Kocher, Nikolaus; Stalke, Dietmar; Kost, Daniel
• Journal of publication: Organometallics
• Year of publication: 2009
• Journal volume: 28
• Journal issue: 2
• Pages of publication: 512 - 516
• a: 8.9891 ± 0.0007 Å
• b: 17.0629 ± 0.0014 Å
• c: 14.9778 ± 0.0012 Å
• α: 90°
• β: 103.867 ± 0.001°
• γ: 90°
• Cell volume: 2230.3 ± 0.3 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0399
• Residual factor for significantly intense reflections: 0.0356
• Weighted residual factors for significantly intense reflections: 0.095
• Weighted residual factors for all reflections included in the refinement: 0.0988
• Goodness-of-fit parameter for all reflections included in the refinement: 1.05
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No