Information card for entry 4063614

Structure parameters

• Common name: 10b
• Chemical name: [N-(dimethylamino)trifluoroacetimidato-N',O]hydridophenylsilicon(IV)
• Formula: C14 H18 F6 N4 O2 Si
• Calculated formula: C14 H18 F6 N4 O2 Si
• SMILES: [SiH]12([N](N=C(O1)C(F)(F)F)(C)C)([N](N=C(O2)C(F)(F)F)(C)C)c1ccccc1
• Title of publication: Reversible Neutral Dissociation of the N‒Si Dative Bond in Hexacoordinate Hydrido Complexes of Silicon
• Authors of publication: Kalikhman, Inna; Kertsnus-Banchik, Evgenia; Gostevskii, Boris; Kocher, Nikolaus; Stalke, Dietmar; Kost, Daniel
• Journal of publication: Organometallics
• Year of publication: 2009
• Journal volume: 28
• Journal issue: 2
• Pages of publication: 512 - 516
• a: 14.9337 ± 0.0009 Å
• b: 7.809 ± 0.0005 Å
• c: 17.1515 ± 0.001 Å
• α: 90°
• β: 115.013 ± 0.001°
• γ: 90°
• Cell volume: 1812.57 ± 0.19 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0348
• Residual factor for significantly intense reflections: 0.0326
• Weighted residual factors for significantly intense reflections: 0.0851
• Weighted residual factors for all reflections included in the refinement: 0.0869
• Goodness-of-fit parameter for all reflections included in the refinement: 1.044
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No