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Information card for entry 4063889
Preview
Coordinates | 4063889.cif |
---|---|
Original paper (by DOI) | HTML |
Common name | [(η^5^-C~5~Me~5~)Ru(=CHCH=CPh~2~){-P(^i^Pr~2~)NH(C~5~H~4~N-)}] |
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Chemical name | {2-(diisopropylphosphinoamine)pyridine-κ^2^-N,P}- (pentahapto-pentamethylcyclopentadienyl) -{(diphenyl)prop-2-en-1-carbene}-ruthenium (II) |
Formula | C37 H48 Cl2 F6 N2 P2 Ru |
Calculated formula | C37 H48 Cl2 F6 N2 P2 Ru |
Title of publication | Nucleophilic Addition Reactions to Allenylidene Complexes of Ruthenium Bearing Hemilabile P,N Ligands: Isolation of the Vinylcarbene Complex [Cp*Ru═CHCH═CPh2(iPr2PNHPy)][PF6] |
Authors of publication | Hyder, Iqbal; Jiménez-Tenorio, Manuel; Puerta, M. Carmen; Valerga, Pedro |
Journal of publication | Organometallics |
Year of publication | 2011 |
Journal volume | 30 |
Journal issue | 4 |
Pages of publication | 726 |
a | 10.376 ± 0.002 Å |
b | 21.655 ± 0.004 Å |
c | 17.28 ± 0.004 Å |
α | 90° |
β | 95.54 ± 0.03° |
γ | 90° |
Cell volume | 3864.5 ± 1.4 Å3 |
Cell temperature | 100 ± 2 K |
Ambient diffraction temperature | 100 ± 2 K |
Number of distinct elements | 7 |
Space group number | 14 |
Hermann-Mauguin space group symbol | P 1 21/c 1 |
Hall space group symbol | -P 2ybc |
Residual factor for all reflections | 0.0494 |
Residual factor for significantly intense reflections | 0.0382 |
Weighted residual factors for significantly intense reflections | 0.0933 |
Weighted residual factors for all reflections included in the refinement | 0.0966 |
Goodness-of-fit parameter for all reflections included in the refinement | 1.027 |
Diffraction radiation probe | x-ray |
Diffraction radiation wavelength | 0.71073 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | Yes |
Has Fobs | No |
For the version history of this entry, please navigate to main COD server.
The link is: https://www.crystallography.net/4063889.html
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Users of the data should acknowledge the original authors of the
structural data.