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Information card for entry 4063890
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Coordinates | 4063890.cif |
---|---|
Original paper (by DOI) | HTML |
Common name | [(η^5^-C~5~Me~5~)Ru{=C(SPH)CH=CPh~2~}{κ^2^ P,N-^i^Pr~2~PNH(C~5~H~4~N)}] [PF~6~].CH~2~Cl~2~ |
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Chemical name | {(diisopropyl-phosphanyl)-(pyridin-2-yl)-amine-κ^2^-P,N}- {1-(phenyl-mercapto)-3,3-diphenylprop-2-en-1-ylidene}- (pentahapto-pentamethyl-cyclopentadienyl)-ruthenium(II) hexafluorophosphate dichloromethane solvate |
Formula | C43 H52 Cl2 F6 N2 P2 Ru S |
Calculated formula | C43 H52 Cl2 F6 N2 P2 Ru S |
Title of publication | Nucleophilic Addition Reactions to Allenylidene Complexes of Ruthenium Bearing Hemilabile P,N Ligands: Isolation of the Vinylcarbene Complex [Cp*Ru═CHCH═CPh2(iPr2PNHPy)][PF6] |
Authors of publication | Hyder, Iqbal; Jiménez-Tenorio, Manuel; Puerta, M. Carmen; Valerga, Pedro |
Journal of publication | Organometallics |
Year of publication | 2011 |
Journal volume | 30 |
Journal issue | 4 |
Pages of publication | 726 |
a | 14.21 ± 0.003 Å |
b | 17.338 ± 0.004 Å |
c | 18.216 ± 0.004 Å |
α | 90° |
β | 104.62 ± 0.03° |
γ | 90° |
Cell volume | 4342.6 ± 1.8 Å3 |
Cell temperature | 100 ± 2 K |
Ambient diffraction temperature | 100 ± 2 K |
Number of distinct elements | 8 |
Space group number | 14 |
Hermann-Mauguin space group symbol | P 1 21/n 1 |
Hall space group symbol | -P 2yn |
Residual factor for all reflections | 0.0526 |
Residual factor for significantly intense reflections | 0.0473 |
Weighted residual factors for significantly intense reflections | 0.1186 |
Weighted residual factors for all reflections included in the refinement | 0.122 |
Goodness-of-fit parameter for all reflections included in the refinement | 1.039 |
Diffraction radiation probe | x-ray |
Diffraction radiation wavelength | 0.71073 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | Yes |
Has Fobs | No |
For the version history of this entry, please navigate to main COD server.
The link is: https://www.crystallography.net/4063890.html
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