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Information card for entry 4063891
Preview
Coordinates | 4063891.cif |
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Original paper (by DOI) | HTML |
Chemical name | {(diisopropyl-phosphanyl)-(pyridin-2-yl)-amine-κ^2^-P,N}-(1-pentafluorophenyl -thio-3,3-diphenyl-prop-2-en-ylidene)-(pentahapto-pentamethyl-cyclopentadienyl) -ruthenium(II) hexafluorophosphate |
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Formula | C42 H45 F11 N2 P2 Ru S |
Calculated formula | C42 H45 F11 N2 P2 Ru S |
Title of publication | Nucleophilic Addition Reactions to Allenylidene Complexes of Ruthenium Bearing Hemilabile P,N Ligands: Isolation of the Vinylcarbene Complex [Cp*Ru═CHCH═CPh2(iPr2PNHPy)][PF6] |
Authors of publication | Hyder, Iqbal; Jiménez-Tenorio, Manuel; Puerta, M. Carmen; Valerga, Pedro |
Journal of publication | Organometallics |
Year of publication | 2011 |
Journal volume | 30 |
Journal issue | 4 |
Pages of publication | 726 |
a | 14.122 ± 0.003 Å |
b | 19.76 ± 0.004 Å |
c | 14.959 ± 0.003 Å |
α | 90° |
β | 101.59 ± 0.03° |
γ | 90° |
Cell volume | 4089.2 ± 1.5 Å3 |
Cell temperature | 100 ± 2 K |
Ambient diffraction temperature | 100 ± 2 K |
Number of distinct elements | 7 |
Space group number | 14 |
Hermann-Mauguin space group symbol | P 1 21/n 1 |
Hall space group symbol | -P 2yn |
Residual factor for all reflections | 0.0878 |
Residual factor for significantly intense reflections | 0.0778 |
Weighted residual factors for significantly intense reflections | 0.1463 |
Weighted residual factors for all reflections included in the refinement | 0.1518 |
Goodness-of-fit parameter for all reflections included in the refinement | 1.061 |
Diffraction radiation probe | x-ray |
Diffraction radiation wavelength | 0.71073 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | Yes |
Has Fobs | No |
For the version history of this entry, please navigate to main COD server.
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