Information card for entry 4065927

Structure parameters

• Formula: C52 H84 As4 Cl2 O16 Pt
• Calculated formula: C52 H84 As4 Cl2 O16 Pt
• SMILES: O(C(C)(C)C)C(=O)C1=C(C(=O)OC(C)(C)C)[As]([Pt]([As]2(C)C(=C([As](C)C(=C2C(=O)OC(C)(C)C)C(=O)OC(C)(C)C)C(=O)OC(C)(C)C)C(=O)OC(C)(C)C)(Cl)Cl)(C)C(=C([As]1C)C(=O)OC(C)(C)C)C(=O)OC(C)(C)C
• Title of publication: 1,4-Dihydro-1,4-diarsinine-Bridged Dinucleartrans-Dihaloplatinum(II) Complexes: Synthesis and Controlled Pt−Pt Interaction by Halogen Substitution Induced Conformational Change§
• Authors of publication: Arita, Manabu; Naka, Kensuke; Shimamoto, Tatsuo; Yumura, Takashi; Nakahashi, Akiko; Morisaki, Yasuhiro; Chujo, Yoshiki
• Journal of publication: Organometallics
• Year of publication: 2010
• Journal volume: 29
• Journal issue: 21
• Pages of publication: 4992
• a: 11.14 ± 0.02 Å
• b: 11.71 ± 0.02 Å
• c: 13.54 ± 0.03 Å
• α: 89.02 ± 0.11°
• β: 71.75 ± 0.13°
• γ: 72.71 ± 0.1°
• Cell volume: 1596 ± 6 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.039
• Residual factor for significantly intense reflections: 0.0343
• Weighted residual factors for significantly intense reflections: 0.0873
• Weighted residual factors for all reflections included in the refinement: 0.091
• Goodness-of-fit parameter for all reflections included in the refinement: 1.079
• Diffraction radiation wavelength: 0.71075 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No