Information card for entry 4065928

Structure parameters

• Formula: C52 H84 As4 Cl4 O16 Pt2
• Calculated formula: C52 H84 As4 Cl4 O16 Pt2
• SMILES: O(C(C)(C)C)C(=O)C1=C([As]2(C)C(=C([As]1(C)[Pt]([As]1(C)C(=C([As](C)(C(=C1C(=O)OC(C)(C)C)C(=O)OC(C)(C)C)[Pt]2(Cl)Cl)C(=O)OC(C)(C)C)C(=O)OC(C)(C)C)(Cl)Cl)C(=O)OC(C)(C)C)C(=O)OC(C)(C)C)C(=O)OC(C)(C)C
• Title of publication: 1,4-Dihydro-1,4-diarsinine-Bridged Dinucleartrans-Dihaloplatinum(II) Complexes: Synthesis and Controlled Pt−Pt Interaction by Halogen Substitution Induced Conformational Change§
• Authors of publication: Arita, Manabu; Naka, Kensuke; Shimamoto, Tatsuo; Yumura, Takashi; Nakahashi, Akiko; Morisaki, Yasuhiro; Chujo, Yoshiki
• Journal of publication: Organometallics
• Year of publication: 2010
• Journal volume: 29
• Journal issue: 21
• Pages of publication: 4992
• a: 10.488 ± 0.003 Å
• b: 11.77 ± 0.004 Å
• c: 13.806 ± 0.006 Å
• α: 77.166 ± 0.018°
• β: 87.327 ± 0.018°
• γ: 80.204 ± 0.017°
• Cell volume: 1637.4 ± 1 ų
• Cell temperature: 99 ± 2 K
• Ambient diffraction temperature: 99 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.08
• Residual factor for significantly intense reflections: 0.0592
• Weighted residual factors for significantly intense reflections: 0.1614
• Weighted residual factors for all reflections included in the refinement: 0.1731
• Goodness-of-fit parameter for all reflections included in the refinement: 1.093
• Diffraction radiation wavelength: 0.71075 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No