Information card for entry 4069701

Structure parameters

• Formula: C63 H73 Li4 N2 O P4 S2 Si2
• Calculated formula: C63 H73 Li4 N2 O P4 S2 Si2
• Title of publication: Synthesis and Structure of [Li2C(PPh2═NSiMe3)(PPh2═S)]: A Geminal Dianionic Ligand
• Authors of publication: Chen, Jun-Hui; Guo, Jiayi; Li, Yongxin; So, Cheuk-Wai
• Journal of publication: Organometallics
• Year of publication: 2009
• Journal volume: 28
• Journal issue: 15
• Pages of publication: 4617
• a: 41.092 ± 0.002 Å
• b: 12.5386 ± 0.0005 Å
• c: 27.4618 ± 0.0014 Å
• α: 90°
• β: 114.819 ± 0.003°
• γ: 90°
• Cell volume: 12842.5 ± 1.1 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 8
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.1522
• Residual factor for significantly intense reflections: 0.0674
• Weighted residual factors for significantly intense reflections: 0.1723
• Weighted residual factors for all reflections included in the refinement: 0.2477
• Goodness-of-fit parameter for all reflections included in the refinement: 1
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No