Information card for entry 4070712

Structure parameters

• Formula: C74 H89 N3 P Rh Si4 Sn
• Calculated formula: C74 H89 N3 P Rh Si4 Sn
• SMILES: [CH]12=[CH]3C4[CH]5=[CH](C1C4)[Rh]235([P](c1ccccc1)(c1ccccc1)c1ccccc1)[Sn]12N(c3cc(cc(c3)C)C)[Si](C)(C)[Si](C)([Si](C)(C)N1c1cc(cc(c1)C)C)[Si](C)(C)N2c1cc(cc(c1)C)C.c1ccccc1.c1ccccc1.c1ccccc1
• Title of publication: Triamidostannates(II) as Sterically Demanding Ligands for Rhodium and Iridium
• Authors of publication: Kilian, Michaela; Wadepohl, Hubert; Gade, Lutz H.
• Journal of publication: Organometallics
• Year of publication: 2008
• Journal volume: 27
• Journal issue: 4
• Pages of publication: 524
• a: 12.983 ± 0.0013 Å
• b: 13.2225 ± 0.0013 Å
• c: 21.979 ± 0.002 Å
• α: 95.447 ± 0.002°
• β: 105.608 ± 0.002°
• γ: 104.915 ± 0.002°
• Cell volume: 3456.5 ± 0.6 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0925
• Residual factor for significantly intense reflections: 0.0501
• Weighted residual factors for significantly intense reflections: 0.112
• Weighted residual factors for all reflections included in the refinement: 0.1272
• Goodness-of-fit parameter for all reflections included in the refinement: 0.99
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No