Information card for entry 4070786

Structure parameters

• Formula: C23 H52 O Si6
• Calculated formula: C23 H56 O Si6
• SMILES: [Si]([C@@H]1/C(=C\C([Si](C)(C)C)[Si](C)(C)C)[Si@](OC)([C@H]([Si](C)(C)C)[C@H]1[Si](C)(C)C)C)(C)(C)C.[Si]([C@H]1/C(=C\C([Si](C)(C)C)[Si](C)(C)C)[Si@@](OC)([C@@H]([Si](C)(C)C)[C@@H]1[Si](C)(C)C)C)(C)(C)C
• Title of publication: An Unexpected Ring Contraction: Phenylsilane to Silacyclopentane
• Authors of publication: Lim, Young Mook; Lee, Myong Euy
• Journal of publication: Organometallics
• Year of publication: 2008
• Journal volume: 27
• Journal issue: 5
• Pages of publication: 1000
• a: 9.5333 ± 0.0015 Å
• b: 13.396 ± 0.002 Å
• c: 14.371 ± 0.002 Å
• α: 82.678 ± 0.003°
• β: 81.324 ± 0.003°
• γ: 70.564 ± 0.002°
• Cell volume: 1705 ± 0.4 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 4
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1166
• Residual factor for significantly intense reflections: 0.0596
• Weighted residual factors for significantly intense reflections: 0.1127
• Weighted residual factors for all reflections included in the refinement: 0.1289
• Goodness-of-fit parameter for all reflections included in the refinement: 0.969
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No