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Information card for entry 4070909
Preview
Coordinates | 4070909.cif |
---|---|
Original paper (by DOI) | HTML |
Formula | C23 H32 Cr O4 Si |
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Calculated formula | C23 H32 Cr O4 Si |
SMILES | [Cr]12345(C#[O])(C#[O])(C#[O])[cH]6[c]3([Si](C)(C)C)[cH]1[cH]2[c]5(O[C@]1(C)C[C@H]2CC[C@]1(C)C2(C)C)[cH]46 |
Title of publication | Toward an Understanding of 1,5-Asymmetric Induction during Nucleophilic Addition to (Arene)chromium Tricarbonyl Complexes: Conformational Preference of the Chromium Tricarbonyl Tripod for Transmission of Chirality |
Authors of publication | Paramahamsan, Harinandini; Pearson, Anthony J.; Pinkerton, A. Alan; Zhurova, Elizabeth A. |
Journal of publication | Organometallics |
Year of publication | 2008 |
Journal volume | 27 |
Journal issue | 5 |
Pages of publication | 900 |
a | 7.7412 ± 0.0006 Å |
b | 10.9198 ± 0.0008 Å |
c | 14.3413 ± 0.001 Å |
α | 90° |
β | 103.896 ± 0.001° |
γ | 90° |
Cell volume | 1176.82 ± 0.15 Å3 |
Cell temperature | 150 ± 1 K |
Ambient diffraction temperature | 150 ± 1 K |
Number of distinct elements | 5 |
Space group number | 4 |
Hermann-Mauguin space group symbol | P 1 21 1 |
Hall space group symbol | P 2yb |
Residual factor for all reflections | 0.0508 |
Residual factor for significantly intense reflections | 0.0508 |
Weighted residual factors for significantly intense reflections | 0.1123 |
Weighted residual factors for all reflections included in the refinement | 0.1123 |
Goodness-of-fit parameter for all reflections included in the refinement | 1.398 |
Diffraction radiation wavelength | 0.71073 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
For the version history of this entry, please navigate to main COD server.
The link is: https://www.crystallography.net/4070909.html
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Users of the data should acknowledge the original authors of the
structural data.