Information card for entry 4070910

Structure parameters

• Formula: C24 H32 Cr O6 Si
• Calculated formula: C24 H32 Cr O6 Si
• SMILES: [Cr]12345([c]6([cH]5[cH]4[c]3([Si](C)(C)C)[cH]2[cH]16)O[C@H]1[C@@]2(CC[C@H](C31OCCO3)C2(C)C)C)(C#[O])(C#[O])C#[O]
• Title of publication: Toward an Understanding of 1,5-Asymmetric Induction during Nucleophilic Addition to (Arene)chromium Tricarbonyl Complexes: Conformational Preference of the Chromium Tricarbonyl Tripod for Transmission of Chirality
• Authors of publication: Paramahamsan, Harinandini; Pearson, Anthony J.; Pinkerton, A. Alan; Zhurova, Elizabeth A.
• Journal of publication: Organometallics
• Year of publication: 2008
• Journal volume: 27
• Journal issue: 5
• Pages of publication: 900
• a: 9.0373 ± 0.0013 Å
• b: 10.5947 ± 0.0015 Å
• c: 25.708 ± 0.004 Å
• α: 90°
• β: 96.084 ± 0.002°
• γ: 90°
• Cell volume: 2447.6 ± 0.6 ų
• Cell temperature: 150 ± 1 K
• Ambient diffraction temperature: 150 ± 1 K
• Number of distinct elements: 5
• Space group number: 4
• Hermann-Mauguin space group symbol: P 1 21 1
• Hall space group symbol: P 2yb
• Residual factor for all reflections: 0.0743
• Residual factor for significantly intense reflections: 0.0631
• Weighted residual factors for significantly intense reflections: 0.113
• Weighted residual factors for all reflections included in the refinement: 0.1173
• Goodness-of-fit parameter for all reflections included in the refinement: 1.077
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No