Information card for entry 4071065

Structure parameters

• Common name: Me2Si(phac-Rh(COD))2
• Chemical name: Bis(1,5-cyclooctadiene)[mu-[3,3'-[dimethylsilylenebis(1,4- phenylene)]bis(2,4-pentanedionato)]dirhodium chloroform solvate
• Formula: C42 H52 Cl6 O4 Rh2 Si
• Calculated formula: C42 H52 Cl6 O4 Rh2 Si
• Title of publication: Organosilicon-Based Multifunctional β-Diketones and their Rhodium and Iridium Complexes
• Authors of publication: Pariya, Chandi; Marcos, Yoseph S.; Zhang, Yixun; Fronczek, Frank R.; Maverick, Andrew W.
• Journal of publication: Organometallics
• Year of publication: 2008
• Journal volume: 27
• Journal issue: 17
• Pages of publication: 4318
• a: 13.507 ± 0.001 Å
• b: 15.562 ± 0.001 Å
• c: 22.709 ± 0.0015 Å
• α: 70.463 ± 0.004°
• β: 86.892 ± 0.003°
• γ: 87.139 ± 0.003°
• Cell volume: 4489.3 ± 0.5 ų
• Cell temperature: 100 K
• Ambient diffraction temperature: 100 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.115
• Residual factor for significantly intense reflections: 0.051
• Weighted residual factors for significantly intense reflections: 0.1091
• Weighted residual factors for all reflections included in the refinement: 0.137
• Goodness-of-fit parameter for all reflections included in the refinement: 0.987
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No