Information card for entry 4071066

Structure parameters

• Common name: MeSi(phac-Rh(COD))3
• Chemical name: tris(1,5-cyclooctadiene)[mu-[3,3',3"-[methylsilylidynetris(1,4- phenylene)]tris(2,4-pentanedionato)]trirhodium toluene solvate
• Formula: C65 H77 O6 Rh3 Si
• Calculated formula: C65 H74 O6 Rh3 Si
• Title of publication: Organosilicon-Based Multifunctional β-Diketones and their Rhodium and Iridium Complexes
• Authors of publication: Pariya, Chandi; Marcos, Yoseph S.; Zhang, Yixun; Fronczek, Frank R.; Maverick, Andrew W.
• Journal of publication: Organometallics
• Year of publication: 2008
• Journal volume: 27
• Journal issue: 17
• Pages of publication: 4318
• a: 6.8596 ± 0.001 Å
• b: 16.044 ± 0.003 Å
• c: 27.2 ± 0.005 Å
• α: 98.156 ± 0.007°
• β: 96.646 ± 0.009°
• γ: 97.498 ± 0.009°
• Cell volume: 2910.3 ± 0.9 ų
• Cell temperature: 90 K
• Ambient diffraction temperature: 90 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.119
• Residual factor for significantly intense reflections: 0.06
• Weighted residual factors for significantly intense reflections: 0.118
• Weighted residual factors for all reflections included in the refinement: 0.138
• Goodness-of-fit parameter for all reflections included in the refinement: 1.022
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No