Information card for entry 4071067

Structure parameters

• Common name: MeSi(phpr-Rh(COD))3
• Chemical name: tris(1,5-cyclooctadiene)[mu-[4,4',4"-[methylsilylidynetris(1,4- phenylene)]tris(3,5-heptanedionato)]trirhodium diethyl ether solvate
• Formula: C68 H91 O7 Rh3 Si
• Calculated formula: C68 H91 O7 Rh3 Si
• Title of publication: Organosilicon-Based Multifunctional β-Diketones and their Rhodium and Iridium Complexes
• Authors of publication: Pariya, Chandi; Marcos, Yoseph S.; Zhang, Yixun; Fronczek, Frank R.; Maverick, Andrew W.
• Journal of publication: Organometallics
• Year of publication: 2008
• Journal volume: 27
• Journal issue: 17
• Pages of publication: 4318
• a: 7.1909 ± 0.0015 Å
• b: 16.858 ± 0.002 Å
• c: 25.998 ± 0.003 Å
• α: 85.689 ± 0.004°
• β: 84.728 ± 0.004°
• γ: 84.439 ± 0.004°
• Cell volume: 3116.5 ± 0.8 ų
• Cell temperature: 90 K
• Ambient diffraction temperature: 90 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.085
• Residual factor for significantly intense reflections: 0.061
• Weighted residual factors for significantly intense reflections: 0.136
• Weighted residual factors for all reflections included in the refinement: 0.152
• Goodness-of-fit parameter for all reflections included in the refinement: 1.028
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No