Information card for entry 4071230

Structure parameters

• Formula: C33 H52 O9 Os3 P2 Pt2
• Calculated formula: C33 H52 O9 Os3 P2 Pt2
• SMILES: [Pt]123([Pt]456([Os]789([Os]%101([Os]247([C]8%10=C(C)C)(C6=O)(C#[O])C#[O])(C3=O)(C#[O])(C#[O])[H]9)([P]5(C(C)(C)C)C(C)(C)C)(C#[O])C#[O])C#[O])[P](C(C)(C)C)(C(C)(C)C)C(C)(C)C
• Title of publication: Cleavage oftert-Butyl Groups from the Tri-tert-butylphosphine Ligand in Osmium−Platinum Carbonyl Cluster Complexes
• Authors of publication: Adams, Richard D.; Boswell, Erin
• Journal of publication: Organometallics
• Year of publication: 2008
• Journal volume: 27
• Journal issue: 9
• Pages of publication: 2021
• a: 15.303 ± 0.002 Å
• b: 13.4145 ± 0.0019 Å
• c: 24.337 ± 0.004 Å
• α: 90°
• β: 95.975 ± 0.003°
• γ: 90°
• Cell volume: 4968.8 ± 1.3 ų
• Cell temperature: 294 ± 2 K
• Ambient diffraction temperature: 294 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0701
• Residual factor for significantly intense reflections: 0.0459
• Weighted residual factors for significantly intense reflections: 0.1264
• Weighted residual factors for all reflections included in the refinement: 0.1437
• Goodness-of-fit parameter for all reflections included in the refinement: 1.099
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No