Information card for entry 4071231

Structure parameters

• Formula: C31 H50 O7 Os3 P2 Pt
• Calculated formula: C31 H50 O7 Os3 P2 Pt
• SMILES: [Pt]12([Os]34([Os]561([Os]173([P]5(C(C)(C)C)C(C)(C)C)([CH]26[C]1(=[CH]47)C)(C#[O])C#[O])(C#[O])C#[O])(C#[O])(C#[O])C#[O])[P](C(C)(C)C)(C(C)(C)C)C(C)(C)C
• Title of publication: Cleavage oftert-Butyl Groups from the Tri-tert-butylphosphine Ligand in Osmium−Platinum Carbonyl Cluster Complexes
• Authors of publication: Adams, Richard D.; Boswell, Erin
• Journal of publication: Organometallics
• Year of publication: 2008
• Journal volume: 27
• Journal issue: 9
• Pages of publication: 2021
• a: 13.7017 ± 0.0007 Å
• b: 10.4238 ± 0.0005 Å
• c: 26.7764 ± 0.0014 Å
• α: 90°
• β: 96.779 ± 0.001°
• γ: 90°
• Cell volume: 3797.6 ± 0.3 ų
• Cell temperature: 294 ± 2 K
• Ambient diffraction temperature: 294 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0395
• Residual factor for significantly intense reflections: 0.0317
• Weighted residual factors for significantly intense reflections: 0.0795
• Weighted residual factors for all reflections included in the refinement: 0.087
• Goodness-of-fit parameter for all reflections included in the refinement: 1.136
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No