Information card for entry 4071849

Structure parameters

• Common name: 5d
• Chemical name: [N-(isopropylideneimino)phenylacetimidato-N',O][N-(isopropylamino)phenylacetimidato-N',O]methylsilicon(IV)
• Formula: C23 H25 N4 O2 Si
• Calculated formula: C23 H30 N4 O2 Si
• SMILES: [Si]12(OC(=N[N]2=C(C)C)Cc2ccccc2)(OC(=NN1C(C)C)Cc1ccccc1)C
• Title of publication: Hydride Migration from Silicon to an Adjacent Unsaturated Imino Carbon: Intramolecular Hydrosilylation
• Authors of publication: Kertsnus-Banchik, Evgenia; Kalikhman, Inna; Gostevskii, Boris; Deutsch, Zvicka; Botoshansky, Mark; Kost, Daniel
• Journal of publication: Organometallics
• Year of publication: 2008
• Journal volume: 27
• Journal issue: 20
• Pages of publication: 5285
• a: 10.356 ± 0.002 Å
• b: 20.348 ± 0.004 Å
• c: 11.087 ± 0.002 Å
• α: 90°
• β: 95.56 ± 0.02°
• γ: 90°
• Cell volume: 2325.3 ± 0.8 ų
• Cell temperature: 140 ± 1 K
• Ambient diffraction temperature: 140 ± 1 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.2241
• Residual factor for significantly intense reflections: 0.1083
• Weighted residual factors for significantly intense reflections: 0.2621
• Weighted residual factors for all reflections included in the refinement: 0.2983
• Goodness-of-fit parameter for all reflections included in the refinement: 0.965
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No