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Information card for entry 4072998
Preview
Coordinates | 4072998.cif |
---|---|
Original paper (by DOI) | HTML |
Formula | C23 H32 B F4 Os P |
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Calculated formula | C23 H32 B F4 Os P |
SMILES | [OsH]1234567([P](C(C)C)(C(C)C)C(=C)C[C]5(C6)=[CH]7c5ccccc5)[cH]5[cH]1[cH]2[cH]3[cH]45.[B](F)(F)(F)[F-] |
Title of publication | One-Pot Dehydrogenative Addition of Isopropyl to Alkynes Promoted by Osmium: Formation of γ-(η3-Allyl)-α-Alkenylphosphine Derivatives Starting from a Dihydride−Dihydrogen−Triisopropylphosphine Complex |
Authors of publication | Esteruelas, Miguel A.; Hernández, Yohar A.; López, Ana M.; Oliván, Montserrat; Oñate, Enrique |
Journal of publication | Organometallics |
Year of publication | 2007 |
Journal volume | 26 |
Journal issue | 9 |
Pages of publication | 2193 |
a | 7.9073 ± 0.0012 Å |
b | 11.2735 ± 0.0017 Å |
c | 13.256 ± 0.002 Å |
α | 98.094 ± 0.002° |
β | 93.655 ± 0.002° |
γ | 104.019 ± 0.002° |
Cell volume | 1129.2 ± 0.3 Å3 |
Cell temperature | 100 ± 2 K |
Ambient diffraction temperature | 100 ± 2 K |
Number of distinct elements | 6 |
Space group number | 2 |
Hermann-Mauguin space group symbol | P -1 |
Hall space group symbol | -P 1 |
Residual factor for all reflections | 0.0375 |
Residual factor for significantly intense reflections | 0.028 |
Weighted residual factors for significantly intense reflections | 0.0538 |
Weighted residual factors for all reflections included in the refinement | 0.0557 |
Goodness-of-fit parameter for all reflections included in the refinement | 0.91 |
Diffraction radiation wavelength | 0.71073 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
For the version history of this entry, please navigate to main COD server.
The link is: https://www.crystallography.net/4072998.html
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Users of the data should acknowledge the original authors of the
structural data.